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                                                TOR-1 deolefination catalyst

                                                TOR-1  reforming reaction oil or aromatic deolefination purification technology

                                                Research Institute of Petroleum Processing

                                                1. Introduction

                                                Catalytic reforming oil is rich in a small amount of olefin. As the reforming severity becomes higher and higher, the olefin content in the reformed oil also increases significantly. Olefin in aromatic hydrocarbon in qualified reforming oil must be removed, or it will affect bromine index, corrosivity, or acid pickling color of aromatic products. A small amount of olefin in the reformed oil has different effects on aromatics extraction and performance of downstream, adsorbent, and catalyst. Thus, how to reduce the olefin content in the reformed oil is a difficult problem to be solved in the industry. Olefin in reforming oil can be removed by the ways of granular argil adsorption, selective hydrogenation and molecular sieve catalytic refining.

                                                 

                                                2. Performance index of TOR-1 catalyst

                                                TOR-1 deolefination catalyst adopts special molecular sieve, with unique pore structure and acid strength distribution, as active component. Single pass life of the catalyst is 8 times that of industrial argil. Compared with argil, TOR-1 has longer life cycle, lower labour intensity, and lower waste emission.

                                                List 1 Physical chemical index of deolefination catalyst TOR-1

                                                Item

                                                Specification

                                                Major component

                                                Molecular sieve and binder

                                                Shape and appearance

                                                Light yellow cylinder

                                                Size, diameter Φ1.4-1.8

                                                3~15mm>80%

                                                Bulk density , g/mL

                                                0.50~0.65

                                                Radial crushing strength , N/cm

                                                ≥100

                                                Specific area, m2/g

                                                ≥500

                                                Pore volume, mL/g

                                                ≥0.35

                                                 

                                                List 2 Operating condition and performance guarantee of deolefination catalyst TOR-1

                                                Item

                                                Index

                                                Reaction materials

                                                After extracting C6/C7 btx aromatics, heptane tower C8+ btx aromatics, isomerous btx aromatics, bromine index of raw material is no more than 1500mgBr/100g。

                                                Reaction weight space velocity, h-1

                                                0.5~2

                                                Reaction pressure, MPa

                                                1~2.5

                                                Reaction temperature, ℃

                                                130~240

                                                Performance guarantee

                                                Bromine index of raw material (mgBr/100g)

                                                Single pass life/entire life

                                                ≤600

                                                ≥10 / ≥30

                                                600~800

                                                ≥8 / ≥24

                                                800~1500

                                                ≥6 / ≥18

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